化合物A的分子式为C4H6O2。它不溶于NaOH溶液,与碳酸钠无作用,可使溴水褪色。它有类似乙酸乙酯的香味。A与NaOH水溶液共热后生成乙酸钠和乙醛。另一种化合物B的分子式与A相同。B不溶于NaOH溶液,与碳酸钠无作用,可使溴水褪色,且有类似乙酸乙酯的香味。但B与NaOH水溶液共热后生成甲醇和一种羧酸钠盐。此钠盐用硫酸中和后蒸馏出的有机物可使溴水褪色。试写出化合物A,B的结构。
化合物A的分子式为C4H6O2。它不溶于NaOH溶液,与碳酸钠无作用,可使溴水褪色。它有类似乙酸乙酯的香味。A与NaOH水溶液共热后生成乙酸钠和乙醛。另一种化合物B的分子式与A相同。B不溶于NaOH溶液,与碳酸钠无作用,可使溴水褪色,且有类似乙酸乙酯的香味。但B与NaOH水溶液共热后生成甲醇和一种羧酸钠盐。此钠盐用硫酸中和后蒸馏出的有机物可使溴水褪色。试写出化合物A,B的结构。
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